Sel Elektrolisis 3–Kompartemen untuk Ekstraksi Magnesium dan Sulfat dari Sistem Larutan MgSO4–KCl–H2O

ABSTRACT: Extraction of  magnesium  and  sulfate  from  MgSO4–KCl–H2O solution system of 0.1 M salt concentration  has been conducted.  The 3–compartment electrolytic cell  model  was  designed  to fulfill the purpose. The cell is constructed from aquarium plastic box of 417 mL capacity divided into  three  compartments.  Each  compartment  is  separated  by  fixed  plastic  wall.  One  of  the compartment  with  no  electrode  (mid  compartment)  was  connected  either  to  anodic  (left)  and cathodic  (right)  compartment  using  double  filter  paper  strip  of  2  x  6  (in  cm)  dimension. Electrolysis  was  performed  in  atmospheric  environment  under  the  6  volt  external  electric potential using 7A Montana power supply.  Experimental results show that electrolysis systems provide  good  separation  of  magnesium  and  sulfate  from  solution.  Magnesium  in  the  form  of Mg(OH)2 and sulfate as  H2SO4 has been obtained in  about 92  %  yield.  Clear solution in the mid compartment  show  the  absence  of  salt  residues;  both  of  cationic  and  anionic  species  migrate totally toward cathodic and anodic compartment respectively.
Penulis: W. H. Rahmanto, M. Asy’ari, Rame, Marihati
Kode Jurnal: jpkimiadd060048

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