Oksidasi Benzilik Alkohol Sekunder dengan Piridinium klorokromat-Alumina

ABSTRACT: In these studies, Pyridinium chlorochromate-Alumina was used for oxidation of secondary alcohols (safryl alcohol and methyleugenyl alcohol) to ketone.  The oxidation of safryl alcohol with PCC-Al2O3 followed by purification by potassium bisulfite yields safryl ketone (62,92%). The oxidation of methyleugenyl alcohol with PCC-Al2O3, followed by purification by potassium bisulfite  yields methyleugenyl ketone (68,04%). The elucidation of these products was analyzed by FTIR, 1H-NMR and MS.
Keywords: PCC-alumina, secondary alcohols, ketone
Penulis: Hanoch J. Sohilait
Kode Jurnal: jpkimiadd080106

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