PEMANFAATAN ARANG BATOK KELAPA DAN TANAH HUMUS BATURRADEN UNTUK MENURUNKAN KADAR LOGAM KROM (Cr)

ABSTRACT: Waste  containing  hazardous  and  toxic  chemical  compounds  into  the  environment leads to water pollution, soil and air. These chemical compounds will endanger human life and  environment.  One  type  of  compound  that  may  pollute the  environment  is  chromium. The  metal  is  commonly  found  in  industrial  waste such as  from  exhaust  and  industrial wastewater from etal plating company.   The purpose of this research is to utilize coconut shell charcoal and soil humus as a low-cost  and  ready-made  alternative  material  to  reduce  the  concentration  chromium  (Cr) on  wastewater.  Humus  was  taken from Baturraden  region  and was isolated  using  NaOH extraction  and  was  furthermore  purified  using  mixtures of  HF(aq):  HCl(aq).  Coconut  shell charcoal was produced and was mixed with the humus. Adsorption process was carried out by  batch  method  on  variations  of  charcoal:  humus  composition,  pH,  and  contact  time. Humus  soil  was  identified  using  infrared  spectrophotometry  (IR).  Determination  of chromium  concentration  was  performed  using  atomic  absorption  spectroscopy  (AAS). The  purified  humus  yielded  was  25.92%  (w/w),  with  34.18%  moisture,  and  ash content  of  18.09%.  The  results  showed  that  the  variation  of  composition  ratio  of  2:1 charcoal and  humus produced the greatest percent reduction of 18.20%, and the optimum pH for the adsorption is 9. For the variation of contacts time, the optimum reaction time is at 180 minutes with decreasing concentration of Pb up to 56.07%.
Keyword: Charcoal, humic substances, adsorption, chromium
Penulis: Anung Riapanitra dan Roy Andreas
Kode Jurnal: jpkimiadd100042

Artikel Terkait :