Efek Adsorpsi Dye ke dalam Lapisan TiO2 dengan Metode Elektroforesis : DSSC Berbasis Lapisan TiO2 Terbuat dengan Metode Slip Casting dan Metode Elektroforesis

Abstract: This  research  aims  to  investigate  the  effect  of  dye  adsorption  into  TiO2  layer  in  dye sensitized  solar  cell  (DSSC),  which  the  TiO2  layer  is  formed  by  slip  casting  and electrophoresis methods. Adsorption process of the dye into the cavities of the TiO2 layer was conducted by  electrophoresis  technique.  As  results,  two  DSSCs  prepared  by  the  slip casting  and  electrophoresis  methods  were  successfully  realized  and  tested.  In  case  of DSSC based on electrophoresis method, XRD results show the appearance of MgO on TiO2 layer,  which  is  probably  caused  by  the  addition  of  salt  Mg(NO3)2  in  the  electrophoresis solution.  Therefore,  electrophoresis  condition  without  the  addition  of  salt  needs  to  be investigated in the next research. It is found that the electrophoresis method can be used in the process of dye adsorption into the TiO2 layer. The electrophoresis with larger voltage results  in  the  larger  DSSC  output.  It  is  also  seen  that  open  circuit  voltage  for  the  slip casting-based  DSSC  is  found  to  be  greater  than  that  for  the  electrophoresis-based  one. This  may be  due  to  the  larger  size  of  the  pores  in  TiO2  layer  for  the slip  casting  process compared to that for the electrophoresis process. For larger size of the pores, the dye can easily fit into the pores with the help of electrophoresis.
Keywords: Dye-sensitized solar cell, Dye adsorption, Electrophoresis, Slip casting
Penulis: Ratno Nuryadi
Kode Jurnal: jpkimiadd110017

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